High-temperature water vapor sensors based on rare-earth-doped barium cerate

Abstract

In this novel study, BaCe0.9Y0.1O3–δ, BaCe0.9Eu0.1O3–δ, BaCe0.9Nd0.1O3–δ, and BaCe0.9Dy0.1O3–δ powders were synthesized by the self-combustion method and processed into thick porous films (60–70 % porosity) to investigate the water vapor sensing properties in the 400–700 °C temperature range. All samples showed a stable response value to water vapor in the whole temperature range, expressed as impedance ratio in dry and wet argon (ZdryAr/ZwetAr), and were able to detect 0.03 vol% of water vapor at 550 °C within the impedance range of 103 Ω at 100 Hz. The response values increased with the partial pressure of water and decreased with the temperature, whereas the maximal value of 3.41 reached the BaCe0.9Eu0.1O3–δ sample at 550 °C and p(H2O) = 4.28 kPa. The average response time was several seconds and only slightly changed with the material type and experimental conditions. The recovery time depended on temperature and the ZdryAr/ZwetAr ratio, whereas the increase in the gas flow rate from 100 cm3/min to 200 cm3/min significantly reduced the recovery time for the BaCe0.9Eu0.1O3–δ sample from 230 s to 55 s at 550 °C and p(H2O) = 2.14 kPa. All the samples exhibited stability and a high degree of reversibility after multiple exchanges of wet and dry atmospheres at different temperatures. Yet, their tendency to deteriorate in the presence of CO2 might challenge a potential application in aggressive environments.