Abstract
Measurements of the high-temperature UV-visible absorption spectra of formaldehyde, chlorobenzene and 1-chloronaphthalene and estimates of their high-temperature photodissociation rates are presented. The photodissociation rate estimates were based on the measured absorption spectra and an assumed direct terrestrial spectral radiant flux for a 1.5 air mass atmosphere. The results indicate a strong dependence of the solar photodissociation rate on the temperature.
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More From: Journal of Photochemistry & Photobiology, A: Chemistry
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