High temperature performances of tri-layer environmental barrier coating with Si bond layer modified by Yb2O3

Abstract

Environmental barrier coatings (EBCs) have been expected to be applied on the surface of ceramic matrix composites (CMCs). However, the oxidation and propagation cracking of the silicon bond layer are the most direct causes to induce the failure of EBCs under high temperature service environment. The modification of silicon bond layer has become an important method to prolong the service life of EBCs. In this work, the Yb2O3 have been introduced to the silicon bond layer, and three kinds of tri-layer Yb2SiO5/Yb2Si2O7/(Si-xYb2O3) EBCs with modified Si bond layer by different contents of Yb2O3 (x = 0, 10 vol%, 15 vol%) were prepared by vacuum plasma spray technique. The thermal shock performance and long-term oxidation resistance of the EBCs at 1350 °C were investigated. The results showed that the addition of appropriate amount of Yb2O3 (10 vol%) can improve the structural stability and reduce the cracks of the mixed thermal growth oxide (mTGO) layer by forming the oxidation product of Yb2Si2O7 during long-term oxidation. The excessive addition of Yb2O3 increased the stress during thermal shock as well as accelerated the oxygen diffusion during long-term oxidation, leading to the failure of EBCs. Moreover, the distribution uniformity of Yb2O3 deserves further consideration and improvement.