Abstract
The high temperature oxidation behavior of plasma sprayed chromium boride-chromium carbide composite coatings had been studied in this work. In-situ and ex-situ CrB2-Cr3C2 composite coatings were prepared by plasma spraying Cr-B4C and CrB2-Cr3C2 composite powders, respectively. The changes of microstructure and phase of two coatings after oxidation at different temperature and time were studied. After oxidation at 850 °C for 10 h, the in-situ Cr-B4C coating had a thinner oxide layer (8–10 μm) and a lower weight gain rate (0.023%) than ex-situ CrB2-Cr3C2 coating. This is because the density of Cr-B4C coating was high, and the oxidized glass phase B2O3 gradually filled the pores of the coating at 850 °C. For oxidation of CrB2-Cr3C2 coating at 1000 °C for 10 h, since the evaporation rate was higher than the generation rate of liquid oxide layers, a large penetration cracks damaged the integrity of the coating surface, which would not hinder oxygen into the coating. The Cr-B4C coating had better oxidation resistance after oxidation at 1000 °C for 10 h, because more phases with low oxygen permeability were formed in the coating, and the generation rate of the oxide film was higher than the evaporation rate.
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