Abstract

Al2O3 composites dispersed with 1, 5, 10, and 15 vol% nickel particles were prepared using a pulsed electric current sintering technique. High-temperature oxidation was conducted at temperatures ranging from 1200°C to 1350°C for 6–24 h in air. After oxidation, the sample surface mainly consisted of NiAl2O4 oxide. The growth of the oxidized zone in all sample groups followed a parabolic pattern. The influence of the Ni content on the high-temperature oxidation behavior of Ni/Al2O3 is discussed. A kinetic model was proposed to explain the growth of the oxidized zone. The diffusion coefficient of oxygen ions through the grain boundaries of the Al2O3 matrix can be obtained using the proposed model, which is in agreement with those in the literature.

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