Abstract
The high-temperature oxidation behavior and mechanical properties of the Yb2Si2O7/Si environmental barrier coatings (EBCs) prepared by plasma spray-physical vapor deposition at 1250 °C and 1350 °C were investigated, and obvious delamination was observed after oxidation for 4000 h. The results showed that element diffusion occurred during oxidation, and the diffusion of oxygen led to the formation of thermal growth oxides (TGO), which induced pores and microcracks. The TGO played a role in hindering element diffusion, but the mismatching coefficients of thermal expansion and phase transition caused vertical and transverse cracks in the TGO layer. These cracks became channels for oxygen diffusion and ultimately resulted in delamination between TGO and the bonding coating (BC) layer. Furthermore, temperature significantly affects the oxidation kinetics of EBCs, and the oxidation within the BC layer alters its elastic modulus. The elastic modulus of the BC layer first increased and then decreased. The oxidation damage was more pronounced at 1350 °C.
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