High temperature H2S selective oxidation on a copper-substituted hexaaluminate catalyst: A facile process for treating low concentration acid gas

Abstract

H2S selective catalytic oxidation technology is a prospective way for the treatment of low concentration acid gas with simple process operation and low investment. However, undesirable results such as large formation of SO2 and catalyst deactivation inevitably occur, due to the temperature rise of fixed reaction bed caused by the exothermic reaction. Catalyst with high activity in wide operating temperature window, especially in high temperature range, is urgently needed. In this paper, a series of copper-substituted hexaaluminate catalysts (LaCux, x = 0, 0.5, 1, 1.5, 2, 2.5) were prepared and investigated for the H2S selective oxidation reaction at high temperature conditions (300-550°C). The LaCu1 catalyst exhibited excellent catalytic performance and great stability, which was attributed to the best reductive properties and proper pore structure. Besides, two facile deep processing paths were proposed to eliminate the remaining H2S and SO2 in the tail gas.