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Abstract
Our own measurements and published experimental data on azomethane (AM) decomposition at 850–1430 K, in conjunction with a theoretical analysis of this reaction, provide convincing evidence for its occurrence via the concerted mechanism in this temperature range. Most of the available experimental data cannot be described within the framework of the classical theory of unimolecular reactions. The need for direct time-resolved low-temperature data on AM decomposition is emphasized.
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