High-temperature corrosion behavior of the FeCrAl laser cladding coatings in waste-to-energy superheaters: Influence of Al content

Abstract

Enhancing the high-temperature corrosion resistance of superheaters in waste-to-energy plants (WTE) is key to improving the efficiency of WTE power generation. The present study employed laser cladding technology to fabricate Fe-13Cr-xAl coatings, and characterized the microstructure, phase structure, and Vickers hardness of the coatings using OM, SEM, XRD, and a Vickers hardness tester. The study investigated the influence of high-temperature corrosion resistance of the coatings under simulated WTE flue gas conditions. This study found that: Al and Cr both exist in the form of solid solution atoms in the laser cladding coatings. The Vickers hardness of the coatings gradually increased with increasing Al content. When the Al content exceeds 10 %, cracks begin to appear in the coatings, and the number and size of cracks increase with increasing Al content. The Fe-13Cr-7Al coatings exhibit the best high-temperature corrosion resistance under simulated WTE flue gas conditions, and it can achieve ∼73 % of the high-temperature corrosion resistance of the Inconel 625 alloy laser cladding coatings. During high-temperature corrosion, phase separation occurs near the grain boundaries, resulting in chromium depletion zones, which promote intergranular corrosion of the coatings. During the process of high temperature corrosion, the reactions between Al, Cl, and S exhibit the lowest Gibbs free energy. The continuous consumption of Al effectively protects the Fe and Cr in the substrate. Additionally, the formation of aluminum oxide in the coating hinders the inward diffusion of Cl2, thereby beneficially impeding the progress of corrosion. Excessive Al contents in the coatings introduced cracks that served as channels for molten salt to penetrate the matrix, thereby reducing the high-temperature corrosion resistance of the coatings.