Abstract
AbstractStyrene/ethyl acrylate (Sty/EA) free‐radical copolymerizations have been conducted in bulk with and without initiator and in solution using p‐xylene and m‐xylene (30 wt% and 60 wt% solvent level) at 100°C and 130°C. The monomer reactivity ratio values and their temperature dependence have been determined from low conversion copolymer composition data using the computer software package RREVM, which is based on the error in variables model (EVM) method. Copolymer composition data at low conversion confirmed the Mayo–Lewis model at both temperatures. The reactivity ratio values of the Sty/EA system do not seem to change with dilution by nonpolar solvents at low concentration from the reactivity ratio values obtained in bulk with and without initiator. However, xylene isomers were found to have a slight effect on the reactivity ratio value of ethyl acrylate when high solvent concentration was utilized. © 2004 Wiley Periodicals, Inc. Adv Polym Techn 23: 186–195, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20009
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
