High-temperature compression deformation behavior of the high Nb-containing TiAl alloys doped with Sn

Abstract

In this work, the high-temperature compression behavior of high Nb-containing TiAl–Sn alloys was investigated at deformed temperatures of 700 °C–1000 °C and strain rates of 0.002 s−1–0.2 s−1. The true stress-strain curves, microstructures, and constitutive equations of TiAl-xSn (x = 0, 0.5, 1, 1.5) alloys under different deformation conditions were systematically compared. Sn addition can increase the flow stress of TiAl alloys at the same deformation temperature, which is caused by the solid solution strengthening effect. At 800 °C/0.002 s−1, the peak flow stress of TiAl–1Sn alloy increases by 180 MPa compared with TiAl–0Sn alloy of 600 MPa. Below the peak stress, the flow stress increases with the increase of strain. Above the peak stress, the flow stress first decreases and then gradually trends to a steady state as the increase of deformation. Furthermore, the Sn addition decreases the brittle-ductile transition temperature of TiAl alloys. The TiAl-xSn (x = 0.5, 1, 1.5) alloys displays obvious flow softening behavior at 700 °C while TiAl–0Sn alloy fractures before reaching the target deformation. The relationship between of the flow stress, strain rate, and deformation temperature for TiAl–0Sn and TiAl–1Sn alloys is suitable for the hyperbolic sinusoidal equation. The dominant softening mechanism of hot deformation for TiAl-xSn (x = 0, 1) alloys is dynamic recrystallization (DRX). The activation energies Q of hot deformation for TiAl–0Sn and TiAl–1Sn alloys are 311 kJ mol−1 and 429 kJ mol−1 at condition of 700–1000 °C/0.002–0.2 s−1, indicating that the TiAl–1Sn alloy exhibits a better stability under the same application condition.