Abstract

In the last 10 years, high temperature calorimetry has allowed a considerable increase in the knowledge of the thermochemistry of metallic systems: determinations of enthalpies of formation of intermetallic compounds or of solid solutions, and of enthalpies of mixing in liquid alloys. The recent extension of the domains of applicability of high temperature calorimetry has been achieved by the development of calorimeters working at increasingly high temperature with very acceptable precision. It must also be pointed out that new methods have been developed for cases where the classical methods failed to obtain reliable results. The purpose of this paper is to emphasize the results obtained recently in systems where the lack of reliable thermochemical information leaves much to be desired.

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