Abstract
Double thorium phosphates MkTh3−k(PO4)4−k (MI = Li, Na, Ag, K, Rb, Tl, Cs; MII = Cd, Ca, Sr, Pb) and thorium phosphate diphosphate Th4(PO4)4P2O7 were synthesized by a high-temperature solid-phase reaction. The double thorium phosphates crystallize in the monoclinic system [space group C2/c for MITh2(PO4)3 and P21/n for MIITh(PO4)2], and the compound Th4(PO4)4P2O7, in the rhombic system (space group Pcam). The bands in the IR spectra were assigned. The double thorium phosphates exhibit high thermal stability. The compounds KTh2(PO4)3, CaTh(PO4)2, and Th4(PO4)4P2O7 were studied by high-temperature X-ray diffraction.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
