Abstract
The article presents the results of a study of high-temperature and electrochemical corrosion of Zn0.5Al alloy doped with calcium in the various media. The thermogravimetric method was used to study the interaction of the Zn0.5Al alloy doped with calcium with atmospheric oxygen in the temperature range 523–623 K in the solid state. The kinetic and energy parameters of the process of high-temperature oxidation of alloys are determined. The process of high-temperature oxidation of Zn-Al-Ca alloys system is characterized by a monotonic decrease in the true oxidation rate and an increase in the effective activation energy when the alloying component in the initial Zn0.5Al alloy is up to 1.0 wt% doping with zinc-aluminum alloy 0.5 and 1.0 wt%. Calcium shows a slight increase in the oxidation rate of alloys. It was revealed that the oxidation process of the studied alloys with oxygen of the gas phase obeys the hyperbolic law. It was found that calcium supplements in the range of 0.01 - 0.1 wt%. The oxidizability of the initial Zn0.5Al alloy is reduced significantly, and the oxidation products of the alloys were ZnO, Al2O3, Al2O3 ∙ ZnO, CaO, Al2O3 ∙ CaO. By potentiostatic methods in the potentiodynamic mode with a potential sweep speed of 2 mV/s, it has been shown that for all samples of the Zn0.5Al-Ca alloys system in the acidic, neutral, and alkaline media, electrochemical potentials of corrosion, pitting formation, and repassivation are shifted to the region of negative values. It was revealed that zinc-aluminum alloys doped with calcium are most resistant to pitting corrosion in all studied media, respectively, in acidic (0.01n.), neutral (0.03-, 0.3-, 3.0 wt%) and alkaline (0.01n.) electrolytes of HCl, NaCl and NaOH. It has been established that calcium additions in the range of 0.01 - 0.1 wt.% reduce the corrosion rate of zinc-aluminum alloy Zn0.5Al by a factor of 2–3. Calcium alloys are recommended as anodic coatings and protectors for corrosion protection of steel products and structures operating at high temperatures.
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