High strength YSZ/YSZ joints bonded with a matching thermal expansion coefficient sealing glass

Abstract

A novel CaO–Al2O3–SiO2–Li2O (CASL) glass was developed for bonding yttria–stabilized zirconia ceramics (YSZ). The CASL glass possessed a coefficient of thermal expansion (CTE) that matched with YSZ and exhibited outstanding wettability on the surface of YSZ substrate. During the bonding process, mutual dissolution and diffusion between YSZ and CASL glass took place, which ensured good interface bonding. Furthermore, the rapid cooling speed led to a completely amorphous seam, which allowed the CTE of the seam to correspond with that of the original glass. The optimal flexural strength of YSZ/YSZ joints could reach more than 90 % of that of the YSZ.