Abstract
As a renewable nanomaterial, transparent nanopaper is one of the promising materials for electronic devices. Although conventional evaporation drying method endows nanopaper with superior optical properties, the long fabrication time limits its widely use. In this work, we propose a multi-stage drying method to achieve high-speed fabrication of clear transparent nanopaper. Drying experiments reveal that nanopaper’s drying process can be separated into two periods. For the conventional single-stage evaporation drying, the drying condition is kept the same. In our newly proposed multi-stage drying, the relative humidity (RH), which is the key parameter for both drying time and haze, is set differently during these two periods. Applying this method in a humidity-controllable environmental chamber, the drying time can be shortened by 35% (from 11.7 h to 7.6 h) while maintaining the same haze level as that from single-stage drying. For a conventional humidity-uncontrollable oven, a special air flow system is added. The air flow system enables decrease of RH by removing water vapor at the water/air interface during the earlier period, thus fabricating clear transparent nanopaper in a relatively short time. Therefore, this humidity-controlled multi-stage drying method will help reduce the manufacturing time and encourage the widespread use of future nanopaper-based flexible electronics.
Highlights
Cellulose nanopaper is composed of only cellulose nanofibers, which are mainly generated from wood [1,2]
The wood chips are purified and disintegrated into micro-sized cellulose pulp fibers, and the pulp fibers are further mechanically nanofibrillated in water to obtain a cellulose nanofiber dispersion
The type of cellulose nanofiber dispersion is the key factor controlling the transparency of the cellulose nanopaper
Summary
Cellulose nanopaper is composed of only cellulose nanofibers, which are mainly generated from wood [1,2]. The cellulose nanofiber dispersion is dried using evaporation or vacuum-filtration-assisted drying to prepare optically transparent cellulose nanopaper [3]. The dispersion containing coarse nanofibers of microfibrillated cellulose can be dried within 12 h by heating after filtration; the obtained nanopaper will be translucent because of its low sheet density [4,5,6]. For the case in which the dispersion only contains fine nanofibers, the obtained nanopaper will be clear transparent with low haze [7]. This outcome is achieved because the fine nanofibers are densely packed, resulting in the absence of cavities and preventing light from scattering inside the sheet [1]
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