Abstract

The decay of highly excited states of xenon after absorption of extreme ultraviolet light is directly tracked via attosecond transient absorption spectroscopy using a time-delayed near-infrared perturbing pulse. The lifetimes of the autoionizing 5$s$5${p}^{6}$6$p$ and 5$s$5${p}^{6}$7$p$ channels are determined to be (21.9 \ifmmode\pm\else\textpm\fi{} 1.3) fs and (48.4 \ifmmode\pm\else\textpm\fi{} 5.0) fs, respectively. The observed values support lifetime estimates obtained by traditional linewidth measurements. The experiment additionally obtains the temporal evolution of the decay as a function of energy detuning from the resonance center, and a quantum mechanical formalism is introduced that correctly accounts for the observed energy dependence.

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