Abstract
The photoassociation spectroscopic data of the long-range molecular 1g state of Cs 2 in the asymptotic range red detuned [-5.02, -2.45 cm -1 ] to the (6S 1/2 +6P 3/2 ) dissociation limit detected using photon counting technique are presented and 18 new high-lying vibrational energy levels are obtained. Fitting experimental data to the improved LeRoy–Bernstein (LRB) formula, we have obtained the long-range molecular coefficient c 3 with a high precision and also demonstrated the necessity of the improved LRB formula for more precise c 3 coefficient by analyzing the residual from fitting procedure.
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