High sensitivity CW-cavity ring down spectroscopy of 12CO 2 near 1.35 μm (I): line positions

Abstract

The absorption spectrum of carbon dioxide in natural isotopic abundance has been investigated by CW-cavity ring down spectroscopy with a new setup based on fibred distributed feedback (DFB) laser diodes. By using a series of 25 DFB lasers, the CO 2 spectrum was recorded in the 7123–7793 cm −1 region with a typical sensitivity of 3×10 −10 cm −1. A 2125 transitions with intensities as low as 1×10 −29 cm/molecule were detected and assigned to the 1 2C 16O 2, 1 6O 1 2C 1 7O and 1 6O 1 2C 1 8O isotopologues. For comparison, only 357 of them were previously reported from Venus spectra and 344 transitions were included in the 2004 version of the HITRAN database. The band by band analysis has led to the determination of the rovibrational parameters of 28, 2 and 6 bands for the 1 2C 16O 2, 1 6O 1 2C 1 7O and 1 6O 1 2C 1 8O isotopologue, respectively. While the uncertainty on the experimental line positions is on the order of 5×10 −4 cm −1, the average deviation from the 1 2C 16O 2 calculated values provided by the most recent version of the carbon dioxide spectroscopic databank (CDSD) is −2.8×10 −3 cm −1 with an root mean square ( rms) deviation of 3.5×10 −3 cm −1. Maximum deviations in the order of 0.02 and 0.12 cm −1 were evidenced for some bands of the 1 6O 1 2C 1 7O and 1 6O 1 2C 1 8O minor isotopologues. The obtained results improve significantly the previous measurements from Venus spectra and will be valuable to refine the sets of effective Hamiltonian parameters used to generate the CDSD database.