Abstract

Inorganic perovskite has attracted great interest due to its excellent optoelectronic properties. There are much less low band gap halide perovskite semiconductors, and CsPbCl3 is one of a wide band gap semiconductor in the perovskite family. In this study, a 0.5-mm CsPbCl3 perovskite single crystal with tetragonal structure and a direct band gap of 2.86 ± 0.3 eV is synthesized by flash evaporation of CsCl-PbCl2 solution. An ultraviolet photodetector based on a CsPbCl3 single crystal is fabricated, showing a photoresponse in a wide wavelength range of 280–435 nm, with a maximum responsivity of 0.272 A/W at 410 nm. Rise and decay response times of the device are less than 28.4 and 2.7 ms, respectively. The good performance of this CsPbCl3 photodetector indicates promising applications in the field of UV optoelectronic devices.

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