High sensitive simultaneous determination of catechol and hydroquinone at mesoporous carbon CMK-3 electrode in comparison with multi-walled carbon nanotubes and Vulcan XC-72 carbon electrodes

Abstract

The simultaneous voltammetric determination of catechol (CC) and hydroquinone (HQ) has been achieved at a mesoporous carbon CMK-3 modified electrode in phosphate buffer solution (pH 7.0). At the electrode both CC and HQ can cause a pair of quasi-reversible and well-defined redox peaks and their peak potential difference increases. In comparison with multi-walled carbon nanotubes (MWCNTs) and Vulcan XC-72 carbon modified electrodes the CMK-3 modified electrode shows larger peak currents and higher adsorbed amounts for the two dihydroxybenzene isomers. This is related to the higher specific surface area of CMK-3. Under the optimized conditions, the linear concentration ranges for CC and HQ are 5 × 10 −7 to 3.5 × 10 −5 M and 1 × 10 −6 to 3 × 10 −5 M, respectively. In the presence of 5 μM isomer, the linear concentration range of CC (or HQ) is 5 × 10 −7 to 2.5 × 10 −5 M (or 5 × 10 −7 to 2.0 × 10 −5 M). The sensitivity for CC or HQ is 41 A M −1 cm −2 or 52 A M −1 cm −2, which is close to that without isomer. The detection limits (S/N = 3) for CC and HQ are 1 × 10 −7 M after preconcentration on open circuit for 240 s.