High Selective Mixed Membranes Based on Mesoporous MCM-41 and MCM-41-NH2 Particles in a Polysulfone Matrix.

Marius Gheorghe Miricioiu,Ciprian Iacob,Violeta-Carolina Niculescu,Gheorghe Nechifor

doi:10.3389/fchem.2019.00332

Abstract

The development of membrane technology for gas separation processes evolved with the fabrication of so-called mixed matrix membranes (MMMs) as an alternative to neat polymers, in order to improve the overall membrane effectiveness. Once the mixed matrix membranes are used, the gas separation properties of the porous materials used as fillers are combined with the economical processability and desirable mechanical properties of polymer matrix. Mixed mesoporous silica/polymer membranes with high CO2 and O2 permeability and selectivity were designed and prepared by incorporating MCM-41 particles into a polymer matrix. Ordered mesoporous silica MCM-41 with high surface confirmed by BET analysis were obtained and functionalized with amino groups. In order to obtain the mixed membranes, the mesoporous silica was embedded into the polysulfone matrix (PSF). Flat mixed matrix membranes with 5, 10, and 20 wt% MCM-41 and MCM-41-NH2 loadings have been prepared via the polymer solution casting method. The phase's interactions were studied using scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transformed infrared spectroscopy (FTIR) and thermogravimetry (TGA), while the gas separation performances were evaluated using pure gases (CO2, O2, N2). The MCM-41/PSF and MCM-41-NH2/PSF membranes exhibited increased permeabilities for O2 (between 1.2 and 1.7 Barrer) and CO2 (between 4.2 and 8.1 Barrer) compared to the neat membrane (0.8 Barrer). The loss of selectivity for the O2/N2 (between 6 and 8%) and CO2/N2 (between 25 and 41%) gas pairs was not significant compared with the pure membrane (8 and 39%, respectively). The MCM-41/PSF membranes were more selective for CO2/N2 than the O2/N2 pair, due to the size difference between CO2 and N2 molecules and to the condensability of CO2, leading to an increase of solubility. Stronger interactions have been noticed for MCM-41-NH2/PSF membranes due to the amino groups, with the selectivity increasing for both gas pairs compared with the MCM-41/PSF membranes.

Highlights

Membrane-based gas separation processes are relatively new technologies and have received significant attention due to their main advantages, such as being environmentally friendly, simplicity, and low operating cost (Zornoza et al, 2009, 2013; Li et al, 2012; Yu et al, 2012; Zhang et al, 2013; Rezakazemi et al, 2014)
The development of the ideal membranes, suitable for gas separation processes, at reasonable costs, remains a challenge that can possibly be overcome by the synthesis of so-called mixed matrix membranes
The main goal of this study was the development of mixed matrix membranes based on mesoporous silica and polysulfone (PSF) polymer and the demonstration of their higher separation performances toward the neat membranes

Summary

Introduction

Membrane-based gas separation processes are relatively new technologies and have received significant attention due to their main advantages, such as being environmentally friendly, simplicity, and low operating cost (Zornoza et al, 2009, 2013; Li et al, 2012; Yu et al, 2012; Zhang et al, 2013; Rezakazemi et al, 2014). These advantages are not enough if the membrane fabrication is laborious and costly, as in the case of inorganic membranes. These are an alternative to commercial neat polymeric membranes and to inorganic membranes, by combining their advantages, such as the easy processability of the polymers, with high gas separation properties of the fillers (Radu et al, 2014)

Objectives

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Conclusion