High resolution vacuum ultraviolet emission spectrum of D2 from 78to103nm: The DΠu1→XΣg+1 and D′Πu−1→XΣg+1 band systems

Abstract

The emission spectrum of the D2 molecule has been studied at high resolution in the vacuum ultraviolet region 78.5–102.7nm. A detailed analysis of the two DΠu1→XΣg+1 and D′Πu−1→XΣg+1 electronic band systems is reported. New and improved values of the level energies of the two upper states have been derived with the help of the program IDEN [V. I. Azarov, Phys. Scr. 44, 528 (1991); 48, 656 (1993)], originally developed for atomic spectral analysis. A detailed comparison is made between the observed energy levels and solutions of coupled equations using the newest ab initio potentials by Wolniewicz and co-workers [J. Chem. Phys. 103, 1792 (1995); 99, 1851 (1993); J. Mol. Spectros. 212, 208 (2002); 220, 45 (2003)] taking into account the nonadiabatic coupling terms for the DΠu1 state with the lowest electronic states BΣu+1, CΠu1, and B′Σu+1. A satisfactory agreement has been found for most of the level energies belonging to the D and D′ states. The remaining differences between observation and theory are probably due to nonadiabatic couplings with other higher electronic states which were neglected in the calculations.