Abstract
The b 0 +− X 2 1 and b 0 +− X 1 0 + subsystems of Seo were excited in a chemiluminescent reaction involving metastable O 2( 1 Δ g) molecules. High-resolution emission spectra were recorded with a Bomem interferometer. Rotational analyses were carried out for four bands of 80SeO, viz., 0-0, 1-1, 0–1, and 1–2. The following equilibrium constants were obtained: bO +, , B e = 0.4571873(7) cm -1, , α e = 0.0037059(9), , cm -1, , r e = 1.663325(1) A ̊ x 21, , B e = 0.4706269(5) cm -1, , α e = 0.0032737(6), , cm -1, , r e = 1.639403(1) A ̊ , W e = 915.59 cm -1, , W eX e = 4.56 cm -1 X 10 + B e = 0.47048 12(5) cm -1, , α e = 0.0032764(6), , cm -1, r e = 1.639657( 1) A ̊ , w.=915.10 cm -1, , W eX e = 4.57 cm -1, where the error limits are 3σ. From the analysis of the line intensities the ratio of the parallel and perpendicular transition moments, μ 0 μ 1 = −1.42 6 was derived.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
