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Abstract
High resolution spectra of the coupled and degenerate (40+, 0) A1 and (40-, 0) B2 (the local mode pair) states of H2Se are reported. The vibration–rotation transitions of H2 n Se (n = 80,78) were assigned by using the ground state combination differences and least-squares fits to yield the rotational and coupling constants for the two stretching states with degenerate band origins: υ0 (40+, 0) = 8894·504cm-1; υ0 (40-, 0) = 8894·504cm-1. Several striking local 0 0 mode limit effects and the formation of fourfold rovibrational energy clusters are observed and discussed.
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