Abstract
Six antimony-phosphates have been studied by MAS high resolution solid state 31P NMR. Correlations have been drawn between NMR chemical shifts and structural data. They show that the 31P resonance line moves towards high field when the number of bridging oxygens in the PO 4, group increases. The chemical shift anisotropy is related to the dimensionality of the solid network. It is smaller for 3D lattices. Water intercalation in layered phosphates leads to a shift of the 31P resonance towards high or low field suggesting that protonation of some (PO 4) 3− group occurs. A correlation between the P-O π bonding and the chemical shift is also proposed.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
