High-resolution resonant Auger spectroscopy of CF 4, SiF 4, and SF 6

Abstract

High-resolution angle-resolved molecular resonant Auger emission from the F 1s excited states of the CF 4, SiF 4, and SF 6 molecules are reported. A number of strong spectator lines resulting into the dissociative final states, whose anisotropy changes by changing the excitation photon energy, dominate the resonant Auger spectra.