Abstract
The high-resolution infrared emission spectrum of sodium monofluoride has been recorded with a Fourier transform spectrometer. A total of 1131 of vibration–rotation transitions, from thev= 1 → 0 tov= 9 → 8 vibrational bands, have been assigned. The infrared data have been combined with existing microwave data in order to obtain improved spectroscopic constants, including DunhamYijandUijcoefficients, for theX1Σ+electronic ground state of NaF.
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