Abstract
The high-resolution infrared emission spectrum of calcium monofluoride has been observed with a Fourier transform spectrometer. A total of 790 rovibrational transitions, from the ν = 1 → 0 to ν = 8 → 7 bands have been assigned. This set of infrared data has been combined with existing microwave data to yield improved Dunham Yij coefficients for the X2Σ+ electronic ground state of CaF.
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