Abstract
The A2Π–X2Σ+ emission band system of the MgCl molecule has been studied by means of high-resolution Fourier transform spectroscopy. Excited MgCl molecules were produced by two different techniques: (i) at Orsay, they were created by mixing Mg vapor with a flow of He/Cl2 and excited in a “heated” Schüller-type discharge tube, and (ii) at Waterloo, they were generated by using a copper hollow cathode lamp loaded with MgCl2 powder. Rovibronic analysis of the (0, 0) and (0, 1) bands was performed. Molecular constants were derived in a weighted nonlinear least squares fit, including both the new line positions and the previously published microwave frequencies (M. Bogey, C. Demuynck, and J. L. Destombes, Chem. Phys. Lett.155, 265 (1989); Y. Ohshima and Y. Endo, Chem. Phys. Lett.213, 95 (1993)).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
