Abstract
The high resolution, laser-induced fluorescence à 2Σ+↔X̃ 2Π spectra of the Ne⋅SH van der Waals complex and its deuterated analog are reported. The rotational analyses provide information about the fine, hyperfine, spin–rotation, and parity interactions in these two complexes. These results are used in conjunction with measured vibrational intervals to develop an empirical potential energy surface for Ne⋅SH/D.
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