Abstract

Zeolites constitute an important class of catalyst materials in the petrochemical industry. Zeolites are aluminosilicates with their framework structures made up of SiO4 (or AlO4) tetrahedra. The catalytic properties such as selectivity and activity are closely related to the structure sensitive properties of zeolites, e.g. shape selectivity, diffusivity, etc. Understanding these properties requires detailed structure characterization of the zeolites. High resolution electron microscopy (HREM) has been successfully applied to solve some zeolite structures when combined with experimental data from other techniques, e.g. absorption experiment. The connectivities of n-member rings in the zeolite frameworks can be directly deduced from the corresponding HREM images. However, radiation damage to the zeolite framework structures by the electron beam necessitates the use of low dose imaging techniques.

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