High-resolution collision energy control through ion position modulation in atom-ion hybrid systems.

Abstract

We demonstrate an ion shuttling technique for high-resolution control of atom-ion collision energy by translating an ion held within a radio-frequency trap through a magneto-optical atom trap. The technique is demonstrated both experimentally and through numerical simulations, with the experimental results indicating control of ion kinetic energies from 0.05 to 1 K with a fractional resolution of ∼10 and the simulations demonstrating that kinetic energy control up to 120 K with a maximum predicted resolution of ∼100 is possible, offering order-of-magnitude improvements over most alternative techniques. Finally, we perform a proof-of-principle chemistry experiment using this technique and outline how the method may be refined in the future and applied to the study of molecular ion chemistry.