High-resolution calorimetric study of the nematic to smectic-Atransition in aligned liquid crystal–aerosil gels

Abstract

High-resolution ac calorimetry has been used to study the nematic to smectic- A (N-SmA) phase transition in the liquid crystal octylcyanobiphenyl (8CB) confined in aligned colloidal aerosil gels. A stable and robust nematic alignment was achieved by repeated thermal cycling of the samples in the presence of a strong uniform magnetic field. In some ways (such as transition temperature and integrated enthalpy), the dependence of the specific heat peak associated with the N-SmA transition on the aerosil density for aligned gels is consistent with that observed in unaligned (random) gel samples. However, a power-law analysis reveals that the behavior of the critical exponent alpha is quite different. For random gels, alpha varies gradually with aerosil density, whereas we find that alpha for aligned gels shifts abruptly to an XY -like value for the lowest aerosil density studied and remains essentially constant as the sil density increases. This aerosil density independence of alpha is consistent with the critical behavior of the smectic correlation lengths obtained from an x-ray scattering study of 8CB in aligned aerosil gels. The combined calorimetric and x-ray results indicate that the role of quenched randomness in aligned gels of 8CB+sils differs significantly from that in random gels.