High rates of hydrogen sulfide emissions measured from marginal oil wells near Austin and San Antonio, Texas

Abstract

Marginal oil and gas wells, or wells that produce less than 15 barrels of oil equivalent per day, represent 80% of actively producing wells in the United States, although they produce less than 10% of energy supply. Marginal wells are a disproportionate source of methane (CH4) relative to their production, and they emit harmful air pollutants, such as benzene and other hydrocarbons found in oil and natural gas. We made direct measurements of CH4 and hydrogen sulfide (H2S) emissions from 46 wellheads in the Luling Field, Caldwell County, Texas, just east of the Austin/San Antonio Metroplex. We found that these wells are venting natural gas and are a large source of hydrogen sulfide (H2S), a poisonous air pollutant. Hydrogen sulfide emission rates ranged from 0 to 5 ± 0.5 g H2S hr−1 with an average emission rate of 1.6 ± 0.1 g H2S hr−1. We also found ambient concentrations of H2S at dangerous levels (>100 ppm) near many of the wells. Methane emission rates were in line with previous studies of marginal wells, ranging from 0.0 to 2770 ± 390 g CH4 hr−1, with a skewed distribution and average emission rate of 710 ± 100 g CH4 hr−1. Oil production records from Texas were incomplete: some wells had oil production data from the year of sampling, but many had no production data for several years or decades, although they were actively pumping while we were on site. Interviews with local residents indicate that the closing of the county gas processing plant and subsequent loss of gathering lines may be the cause of gas venting and CH4 and H2S emissions from production sites. This deserves further scrutiny, as marginal wells in this region are a major source of H2S, a health hazard to people living and working nearby.