High-pressure synthesis and superconductivity of the novel laves phase BaIr2

Abstract

Superconductors comprising 5d transition metals of Ir and Pt have been widely explored because they have the potential of unique superconductivity caused by the strong spin-orbit interaction (SOI). We successfully synthesized BaIr2, the last Laves phase remaining unsynthesized in the MgCu2-type AM2 (A = Ca, Sr, Ba; M = Rh, Pd, Ir, Pt). BaIr2 was crystallized at 925 °C under a pressure of 3.3 GPa via a solid-state reaction between Ba and Ir powders; it was found to have the longest a-lattice constant of 8.038 (1) Å among AM2. BaIr2 exhibited bulk superconductivity at a transition temperature (Tc) of ∼2.7 K BaIr2 was found to have a type-II superconductor with an upper critical field of 67.7 kOe, which was above the Pauli paramagnetic limit (∼50 kOe). The electron–phonon coupling constant and normalized specific heat jump were measured to be 0.63 and 1.2, respectively, indicating that BaIr2 is a weak-coupling superconductor. The electronic-structure calculations for BaIr2 revealed that the Ir-5d states are dominant at the Fermi energy (EF) and the density of states at the EF is strongly affected by SOI as in the case of CaIr2 and SrIr2.