Abstract
Free trade: The electron exchange of cytochrome c freely diffusing to gold electrodes modified by hydroxy-terminated alkanethiol self-assembled monolayers (SAMs; see picture) is examined by high-pressure kinetic studies. The SAM thickness, solution viscosity, and hydrostatic pressure influence a changeover in the charge-transfer mechanism and the corresponding kinetic response. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z502386_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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