Abstract
An exploratory high-pressure study of the join CaTiO3-FeTiO3 has uncovered two intermediate perovskites with the compositions CaFe3Ti4O12 and CaFeTi2O6. These perovskites have ordering of Ca2+ and Fe2+ on the A sites. Both of these perovskites are unusual in that the A sites containing Fe2+ are either square planar or tetrahedral, due to the particular tilt geometries of the octahedral frameworks.
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