Abstract

The results of an investigation of ion/molecule reactions in gaseous mixtures of ammonia and argon, and pure ammonia are presented. Relative values of the ion currents for observed ions were determined as a function of the gas pressure in the ion source collision chamber, and of the concentration of ammonia in the mixture. The reaction rate constants for NH + 3, NH + 2 and NH + ions in pure ammonia were determined. Measurements were performed using a mass spectrometer with the high pressure ion source constructed by the authors.

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