Abstract
We have recently shown that the high-pressure behavior of the isothermal compressibility, κT, and the thermal expansion coefficient, αp, can be characterized for molecular liquids from low-pressure measurements of these quantities together with surface tension data. The quality of the estimation was good enough to characterize the pressure behavior of the molar volume using a reference volume measured under orthobaric conditions. The same scheme is used here to predict the molar volume of some binary mixtures at different compositions as a function of pressure. Agreement with experimental data is good enough to predict the high-pressure behavior of the molar excess volume. © 1995 American Chemical Society.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
