Abstract
A multicomponent olivine cathode material, LiMn0.4Fe0.6PO4 , was synthesized via a novel coprecipitation method of the mixed transition metal oxalate. X-ray diffraction patterns indicate that carbon-coated LiMn0.4Fe0.6PO4 has been prepared successfully and that LiMn0.4Fe0.6PO4/C is crystallized in an orthorhombic structure without noticeable impurity. Homogeneous distribution of Mn and Fe in LiMn0.4Fe0.6PO4/C can be observed from the scanning electron microscopy (SEM) and the corresponding energy dispersive X-ray spectrometry (EDS) analysis. Hence, the electrochemical activity of each transition metal in the olivine synthesized via coprecipitation method was enhanced remarkably, as indicated by the galvanostatic charge/discharge measurement. The synthesized LiMn0.4Fe0.6PO4/C exhibits a high capacity of 158.6 ± 3 mAhg-1 at 0.1 C, delivering an excellent rate capability of 122.6 ± 3 mAhg-1 at 10 C and 114.9 ± 3 mAhg-1 at 20 C.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
