High-Potential Redox Shuttle for Use in Lithium-Ion Batteries

Abstract

Redox shuttle additives can be used in lithium-ion cells to protect against overcharging and for cell balancing in multicell packs. Most previously reported redox shuttles have been either unstable as shuttles, resulting in a short duration of overcharge protection, or have redox potentials that make them suitable only for cells containing lower potential positive electrode materials, such as . A new molecule, 1,4-di--butyl-2,5-bis(2,2,2-trifluoroethoxy)benzene, is shown here to be a stable redox shuttle with a redox potential of and provides overcharge protection in full Li-ion cells, implying adequate reductive stability. Experiments using and cells show that this molecule can work with high-energy-density positive electrodes as well as in full cells containing positive electrodes and Li, mesocarbon microbead, or negative electrodes.