High performance yttria-stabilized zirconia based intermediate temperature solid oxide fuel cells with double nano layer composite cathode

Abstract

A composite double layer cathode of La0.6Sr0.4Co0.8Fe0.2O3−δ/La0.8Sr0.2FeO3−δ (LSCF/LSF) was successfully fabricated by infiltration method to accelerate the sluggish oxygen reduction reaction (ORR) processes. In this composite cathode, both LSF and LSCF layers are uniformly distributed on Yttria-stabilized Zirconia (YSZ) scaffold by optimizing the infiltrating solution components. LSF serves as a protective layer between LSCF and YSZ. The introduction of the LSCF exterior layer has greatly improved cell performance compared with the cell with sole LSF cathode. At 600 °C, the maximum power density of the cell with LSCF/LSF/YSZ composite cathode reaches up to 0.559 W cm−2. The evolution of the cathode polarization resistance verifies that the ORR activity has been greatly enhanced. Therefore, the results indicate that the high cell performance at intermediate temperatures can be obtained by adopting the LSCF cathode into YSZ-based SOFCs using protective layer and that the infiltration method is a practical way for constructing electrode.