High performance three-phase boundary obtained by sand blasting technology for mixed-potential-type zirconia-based NO2 sensors

Abstract

High sensitive mixed-potential-type NO2 sensors based on yttria-stabilized zirconia (YSZ) electrolyte with high performance TPB (three-phase boundary) were fabricated. The sand blasting technology was utilized to construct high performance TPB on smooth YSZ-substrates. The SiC sand with different diameter (40, 60 and 80μm) was used to process YSZ substrate for improving the surface topography of YSZ. The results from SEM (scanning electron microscope) observation and roughness measurement showed that surface roughness of YSZ substrate increased with the increasing of SiC sand diameter. And a high performance three-phase boundary was constructed to enhance the sensitivity of the sensor. In comparison with other sensors, the sensor using the YSZ-substrate processed by 80μm SiC gave the largest signal to NO2 at 850°C, whose response to 100ppm NO2 was about 1.08, 1.21 and 1.5 times higher than those for the sensors based on YSZ-substrate blasted by 60μm SiC, 40μm SiC and the smooth YSZ substrate, respectively. It was also seen that the sensor showed a good stability and speedy response kinetics. The improvement of NO2-sensing properties might be due to the enlargement of the area of three-phase boundary.