High-Performance Photocatalytic Reduction of Nitrogen to Ammonia Driven by Oxygen Vacancy and Ferroelectric Polarization Field of SrBi4 Ti4 O15 Nanosheets.

Abstract

Photo-responsive semiconductors can facilitate nitrogen activation and ammonia production, but the high recombination rate of photogenerated carriers represents a significant barrier. Ferroelectric photocatalysts show great promise in overcoming this challenge. Herein, by adopting a low-temperature hydrothermal procedure with varying concentrations of glyoxal as the reducing agent, oxygen vacancies (Vo) are effectively produced on the surface of ferroelectric SrBi4 Ti4 O15 (SBTO) nanosheets, which leads to a considerable increase in photocatalytic activity toward nitrogen fixation under simulated solar light with an ammonia production rate of 53.41µmol g-1 h-1 , without the need of sacrificial agents or photosensitizers. This is ascribed to oxygen vacancies that markedly enhance the self-polarization and internal electric field of ferroelectric SBTO, and hence, facilitate the separation of photogenerated charge carriers and light trapping as well as N2 adsorption and activation, as compared to pristine SBTO. Consistent results are obtained in theoretical studies. Results from this study highlight the significance of surface oxygen vacancies in enhancing the performance of photocatalytic nitrogen fixation by ferroelectric catalysts.