High-performance P2-Na0.67Mn0.85Cu0.15O2/Hard carbon full cell Na-ion battery: Pre-Sodiation of anode, p/n ratio optimizations, and Operando XAS studies

Abstract

Na-ion batteries have gained significant attention as a cost-effective and efficient energy storage option for large scale applications, serving as an alternative to the Li-ion batteries. However, commercialization of these batteries is still many steps away since most cathode materials suffer from significant capacity loss and more full-cell studies are required. In this work, we report the electrochemical properties of half- and full-cells of P2-type Na0.67Mn0.85Cu0.15O2 synthesized by solid state technique. X-ray diffraction, FT-IR, and Raman spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy techniques are used to determine the structural properties. Surface properties are studied by X-ray photoelectron spectroscopy and Brunauer–Emmett–Teller techniques. Half cells and full cells were constructed with Na-metal and hard carbon, respectively. Na-ion diffusion kinetics at 10 °C, room temperature, and 50 °C were determined experimentally. Galvanostatic cycling tests on half-cells show capacity values of 165/124 mAh/g for the 1./100. cycles with 24.8 % capacity fade. Operando x-ray absorption spectroscopy measurements were utilized to study local structural modification around transition metal ions during charge/discharge. In the full-cell studies, electrode mass ratio (p/n) and parameters for presodiation of hard carbon were optimized. Using 30 mA/g current density, the unprocessed and the pre-sodiated full-cells reach capacity values of 48 mAh/g (p/n = 2.5) and 150 mAh/g (p/n = 0.75 and 1.15), respectively.