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Abstract
The phenolic oxidative coupling of morphine and related opiates to yield fluoescent products, used for post-column high-performance liquid chromatography detection, has been studied in micellar solutions. The nonionic surfactant, Triton X-100, was found to enhance the detection limit. This enhancement was a result of increased coupling rather than increased fluorescent response of the morphine dimer, pseudomorphine. Ionic surfactants either reduce the sensitivity of detection, or were not applicable to the reaction system used.
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