Abstract
The high-performance liquid chromatography of fourteen rhenium complexes with phosphorus and 2,2′-bipyridine-derivative ligands has been examined. Good separation between these complexes was achieved by use of an ODS column with a 60∶40 (v/v) mixture of MeOH and KH2PO4-NaOH buffer as mobile phase. Linear correlations were observed between the capacity factors of the mono-phosphorus complexes and Fujita's organicity/inorganicity ratios for the phosphorus ligands, revealing that Fujita's organicity/inorganicity parameters are useful for evaluating of the retention behavior of these complexes.
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