High-Performance Heat Storage Phase Change Composite by Highly Aligned N-Doped Mesoporous Carbon for Efficient Battery Thermal Management

Abstract

Limited by leakage from inherent liquid to solid phase transition and inferior heat transfer, pristine organic phase change materials (PCMs) possess extremely low thermal storage performance. Thus, establishing shape-stable PCM composites with enhanced thermal conductivity and latent heat is a key task for practical application. Herein, we constructed N-doped mesoporous carbon monoliths with a highly aligned structure by directional freeze-drying to encapsulate polyethylene glycol. Benefiting from the mesoporous carbon matrix and pyridinic N from N-doping, the PCM composite possessed large latent heat (140 J·g–1) and leakage proof at 80 °C. Meanwhile, the highly aligned structure created a fast heat transfer pathway that improved thermal conductivity of the PCM composite by 1500%. Being different from most research studies, highly aligned carbon was utilized as the support directly without skeletons, which could increase PCM loading capacity and thermal conductivity as well. The PCM composite can be employed as promising candidates for thermal management working efficiently to decrease battery pack temperature by 13 °C and improve discharge capacity by 28%.