Abstract
The introduction of alkyl chains into the luminescent molecules will increase solubility and film-forming performance for fabricating solution-processed organic semiconductor devices. In this work, 5CzBN-9CSP and 5CzBN-12CSP with long alkyl chains were synthesized based on the typical thermally activated delayed fluorescence (TADF) molecule 5CzBN as core, and bipolar 9,9′-spirobi[fluorene] (SP) groups as peripheral dendrons. Not only the excellent solution processability is invested, but also the uniform photophysical property is sustained, including small singlet-triplet splitting energy (ΔEST) and high reverse intersystem crossing (RISC) rate. However, excessive length of alkyl chains degrading thermodynamic stability and carrier transport and balance, results in a maximum external quantum efficiency (EQEmax) of 17.6% for 5CzBN-12CSP-based fully solution-processed non-doped device, which is lower than that for 5CzBN-9CSP counterpart. Furthermore, TADF sensitized (TSF) solution-processed device obtains a high EQEmax of 25.9% within 5CzBN-12CSP host and multiple-resonance (MR) final emitter thanks to an efficient energy transfer.
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